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<b><span style="font-size:14.0pt; line-height:200%">NAME: </span></b><span style="font-size:14.0pt; line-height:200%">Wenyue Ding</span><span style="font-family:"Calibri","sans-serif""></span></p>
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<b><span style="font-size:14.0pt; line-height:200%">DATE: </span></b><span style="font-size:14.0pt; line-height:200%">Monday, June 3, 2019</span><span style="font-family:"Calibri","sans-serif""></span></p>
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<b><span style="font-size:14.0pt; line-height:200%">TIME:</span></b><span style="font-size:14.0pt; line-height:200%"> 10:00 AM</span><span style="font-family:"Calibri","sans-serif""></span></p>
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<b><span style="font-size:14.0pt; line-height:200%">PLACE: </span></b><span style="font-size:14.0pt; line-height:200%">Chemical Engineering Conference Room (S234)</span><span style="font-family:"Calibri","sans-serif""></span></p>
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<b><span style="font-size:14.0pt; line-height:200%">CHAIR/ADVISOR: </span></b><span style="font-size:14.0pt; line-height:200%">Dr. Megan Robertson</span><span style="font-family:"Calibri","sans-serif""></span></p>
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<b><span style="font-size:14.0pt; line-height:200%">Improving Mechanical Properties of Sustainable Thermoplastic Elastomers</span></b></p>
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Thermoplastic elastomers (TPEs), predominantly composed of ABA triblock copolymers containing glassy polystyrene endblocks and rubbery polydiene midblocks, are widely used in electronics, adhesives and automotive components. Sustainable TPEs derived from renewable
resources can be attractive alternatives to petroleum-based TPEs when sustainability requirements are met without compromising material performance. Vegetable oils and their fatty acids are promising replacements for petroleum sources as polymer feedstocks
due to their abundance, lack of toxicity and ease of functionalization. However, fatty acid-derived TPEs exhibit inferior mechanical properties to petroleum-based products due to lack of entanglements, stemming from the presence of long alkyl chains on the
fatty acids. To facilitate the adoption of polymers derived from vegetable oils and fatty acids, we aim to develop approaches to enhance the mechanical properties of this class of materials.</p>
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In this study, two approaches were evaluated as means to enhance the mechanical properties of sustainable TPEs with fatty acid-derived midblocks: incorporation of hydrogen bonds or ionic interactions. In the first approach, the hydrogen bond-containing comonomer
acrylamide was incorporated into midblock. The triblock copolymers exhibited not only greatly improved mechanical properties, but also accessible processing temperatures. In the second approach, ionic interactions were introduced into midblock by neutralizing
the comonomer methacrylic acid. The tensile strength and modulus were significantly enhanced by the incorporation of ionic interactions and the strain at break was improved at low degrees of neutralization.
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