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<h2><span style="font-family:Tahoma">PhD Dissertation Announcement<o:p></o:p></span></h2>
<p class="MsoNormal"><b><span style="font-size:11.0pt;mso-bidi-font-size:10.0pt;
font-family:Tahoma"> </span></b></p>
<p class="MsoNormal" align="center" style="text-align:center"><b><span style="font-size:14.0pt;font-family:Tahoma">Application of
Gettering Layers for Low Temperature Conversion of Magnetic Oxides into
Ferromagnetic Metals in Thin Films, Multilayers, and Nanostructured Arrays<o:p></o:p></span></b></p>
<p class="MsoNormal" align="center" style="text-align:center"><b><span style="font-size:14.0pt;font-family:Tahoma;mso-fareast-language:
ZH-CN">Wenlan Qiu<o:p></o:p></span></b></p>
<p class="MsoNormal" align="center" style="text-align:center"><b><span style="font-size:12.0pt;font-family:Calibri;mso-bidi-font-family:
Tahoma"> </span></b></p>
<p class="MsoNormal" align="center" style="text-align:center"><b><span style="font-size:12.0pt;font-family:Calibri;mso-bidi-font-family:
Tahoma;mso-fareast-language:ZH-CN">July 27 2015<o:p></o:p></span></b></p>
<p class="MsoNormal" align="center" style="text-align:center"><b><span style="font-size:12.0pt;font-family:Calibri;mso-bidi-font-family:
Tahoma">SERC 1016<o:p></o:p></span></b></p>
<p class="MsoNormal" align="center" style="text-align:center"><b><span style="font-size:12.0pt;font-family:Calibri;mso-bidi-font-family:
Tahoma">11:15 AM<o:p></o:p></span></b></p>
<p class="MsoNormal" align="center" style="text-align:center"><b><span style="font-size:12.0pt;font-family:Calibri;mso-bidi-font-family:
Tahoma"> </span></b></p>
<p class="MsoNormal" align="center" style="text-align:center"><b><span style="font-size:12.0pt;font-family:Calibri;mso-bidi-font-family:
Tahoma">Committee Chair: </span></b><span style="font-size:12.0pt;font-family:Calibri;mso-bidi-font-family:Tahoma">Dr.
Dmitri Litvinov<o:p></o:p></span></p>
<p class="MsoNormal" align="center" style="text-align:center"><b><span style="font-size:12.0pt;font-family:Calibri;mso-bidi-font-family:
Tahoma"> </span></b></p>
<p class="MsoNormal" align="center" style="text-align:center"><b><span style="font-size:12.0pt;font-family:Calibri;mso-bidi-font-family:
Tahoma">Committee Members:<o:p></o:p></span></b></p>
<p class="MsoNormal" align="center" style="text-align:center"><span style="font-size:12.0pt;font-family:Calibri;mso-bidi-font-family:Tahoma">Dr.
Paul R</span><span style="font-size:12.0pt;font-family:Calibri;mso-bidi-font-family:
Tahoma;mso-fareast-language:ZH-CN">uchhoeft<o:p></o:p></span></p>
<p class="MsoNormal" align="center" style="text-align:center"><span style="font-size:12.0pt;font-family:Calibri;mso-bidi-font-family:Tahoma;
mso-fareast-language:ZH-CN">Dr. Stanko R. Brankovic<o:p></o:p></span></p>
<p class="MsoNormal" align="center" style="text-align:center"><span style="font-size:12.0pt;font-family:Calibri;mso-bidi-font-family:Tahoma;
mso-fareast-language:ZH-CN">Dr. Gila Stein<o:p></o:p></span></p>
<p class="MsoNormal" align="center" style="text-align:center"><span style="font-size:12.0pt;font-family:Calibri;mso-bidi-font-family:Tahoma;
mso-fareast-language:ZH-CN">Dr. Long Chang<o:p></o:p></span></p>
<p class="MsoNormal"><span style="font-size:12.0pt;font-family:Calibri;
mso-bidi-font-family:Tahoma;mso-fareast-language:ZH-CN"> </span></p>
<p class="MsoNormal" style="text-align:justify;text-justify:inter-ideograph;
text-indent:.5in"><span style="font-size:11.0pt;font-family:Calibri;mso-bidi-font-family:
Tahoma;mso-fareast-language:ZH-CN">Nanoscale patterning of magnetic metals and
their alloys remains a significant challenge due to the lack of reactive-ion
etching chemistries producing volatile compounds of magnetic elements.
Patterning is typically achieved either via a pre-etched substrate deposition,
lift-off process, ion milling, or wet etching, all lacking the needed fidelity
to achieve the high resolution and high areal density because of fabrication
issues such as fencing, shadowing, edge damage, redeposition, or magnetic
material residual. Alternatively, electrochemical deposition may circumvent
these fabrication issues and produce high aspect ratio structures, but is difficult
to make complex structures, i.e. Co/Pd or Co/Pt multilayers, and CoCrPtX
alloys, which are widely studied to be the potential candidates for magnetic
recording media with areal density beyond 1 Tb/in<sup>2</sup>. <o:p></o:p></span></p>
<p class="MsoNormal" style="text-align:justify;text-justify:inter-ideograph;
text-indent:.5in"><span style="font-size:11.0pt;font-family:Calibri;mso-bidi-font-family:
Tahoma;mso-fareast-language:ZH-CN">This work demonstrates conversion of
nonmagnetic cobalt oxide (CoO) into ferromagnetic cobalt (Co) in thin films,
multilayers, and nanostructured arrays by low temperature annealing in the
presence of tantalum (Ta) gettering layers. Thin film of CoO sandwiched between
Ta seed and capping layers can be effectively reduced to a magnetic Co thin
film by annealing at 200 °C, whereas CoO does not exhibit ferromagnetic
properties at room temperature and is stable at up to ~ 400 °C. The CoO
reduction is attributed to the thermodynamically driven gettering of oxygen by
Ta, similar to the exothermic reduction-oxidation reaction observed in thermite
systems. Likewise, annealing at 200 °C of a nonmagnetic CoO/Pd multilayer
results in the conversion into a magnetic Co/Pd multilayer with perpendicular
anisotropy. A nanopatterning approach is introduced where CoO/Pd multilayer is
locally reduced into Co/Pd multilayer to achieve magnetic nanostructured array.
This technique can potentially be adapted to nanoscale patterning of other
systems for which thermodynamically favorable combination of oxide and
gettering layers can be identified.<o:p></o:p></span></p>
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