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<p class="TTPAuthors" style="margin-top: 0in; margin-right: -0.7pt; "><b><span style="font-family: Times; ">Seminar: Science and Technology of Multifunctional
Oxide and Ultrananocrystalline Diamond (UNCD) Films and Applications to a <o:p></o:p></span></b></p>
<p class="TTPAuthors" style="margin-top: 0in; margin-right: -0.7pt; "><b><span style="font-family: Times; ">New Generation of Multifunctional High-Tech
and Medical Devices</span></b><span style="font-family:Times;mso-bidi-font-family:
"Times New Roman";mso-fareast-language:ZH-CN"><o:p></o:p></span></p><p class="TTPAuthors" style="margin-top: 0in; margin-right: -0.7pt; "><b><span style="font-family: Times; ">5/5/2015 at 2pm in W122-D3</span></b></p>
<p class="TTPAddress" align="left" style="margin-top:0in;text-align:left"><b><span style="font-size:12.0pt;mso-bidi-font-size:
11.0pt;font-family:Times;mso-fareast-language:ZH-CN"> </span></b></p>
<p class="MsoBodyText2" align="center" style="margin-right:-.95pt;text-align:center"><b><span style="font-family:Times">Orlando
Auciello</span></b><span style="font-family:Times"><o:p></o:p></span></p>
<p class="MsoBodyText2" align="center" style="margin-right:-.95pt;text-align:center"><b><span style="font-size:11.0pt;mso-bidi-font-size:
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<p class="MsoBodyText2" align="center" style="margin-right:-.95pt;text-align:center"><span style="font-size:11.0pt;font-family:Times">Endowed Chair Professor<o:p></o:p></span></p>
<p class="MsoBodyText2" align="center" style="margin-right:-.95pt;text-align:center"><span style="font-size:11.0pt;font-family:Times">(AAAS AND MRS Fellow)<o:p></o:p></span></p>
<p class="MsoBodyText2" align="center" style="margin-right:-.95pt;text-align:center"><span style="font-size:11.0pt;font-family:Times">(President of the Materials Research
Society-2013)<o:p></o:p></span></p>
<p class="MsoBodyText2" align="center" style="margin-right:-.95pt;text-align:center;
tab-stops:center 3.25in left 420.5pt"><span style="font-size:11.0pt;font-family:
Times">University of Texas at Dallas, Departments of Materials Science and
Engineering and Bioengineering<o:p></o:p></span></p>
<p class="TTPAddress" style="margin-top:0in"><span lang="FR" style="font-family:
Times;mso-ansi-language:FR;mso-fareast-language:ZH-CN">E-</span><span lang="FR" style="font-family:Times;mso-ansi-language:FR">mail</span><span lang="FR" style="font-family:Times;mso-ansi-language:FR;mso-fareast-language:ZH-CN">: orlando.auciello@utdallas.edu;
Tel.: 972-883-4731<o:p></o:p></span></p><p class="TTPAddress" style="margin-top:0in"><span lang="FR" style="font-family:Times;mso-ansi-language:FR;mso-fareast-language:ZH-CN"><br></span></p>
<p class="TTPAddress" style="margin-top:0in"><span lang="FR" style="font-size:1.0pt;
mso-bidi-font-size:10.0pt;font-family:Times;mso-ansi-language:FR;mso-fareast-language:
ZH-CN"> </span></p>
<p class="MsoNormal" style="margin-right:-.5in;text-align:justify;text-justify:
inter-ideograph"><span lang="DE">Auciello graduated with M.S. (1973) and Ph.D
(1976) degrees in Physics from the Physics Institute “Dr. Balseiro” (Universidad
Nacional de Cuyo, Argentina). Electronic Engineering at the University of
Córdoba-Argentina (1964-1970). <o:p></o:p></span></p>
<p class="MsoNormal" style="margin-right:-.5in;text-align:justify;text-justify:
inter-ideograph"><span lang="DE">Auciello was Researcher at the University of
Toronto-Canada (1979-1984), Associate Professor at North Carolina State
University (1985-1988), and Senior Research Scientist at the Microelectronics
Center of North Carolina (1988-1996). He was a Senior Scientist at Argonne
National Laboratory (1996-2005) and Distinguished Argonne Fellow (2005-2012).
He is an Adjunct Professor at University of Colorado-Colorado Springs and
Michigan State University.<o:p></o:p></span></p>
<p class="MsoNormal" style="margin-right:-.5in;text-align:justify;text-justify:
inter-ideograph"><span lang="DE">He is directing basic and applied research
programs on different fields, involving multi-component oxide thin films and
application to systems and devices (ferroelectric memories, resistive change
memories, nanoscale CMOS devices, photovoltaic energy generation / storage
devices, high-frequency devices, piezoelectric thin films for MEMS/NEMS sensors
and actuators); and nanocarbon thin films (ultrananocrystalline diamond (UNCD)
and graphene films) and applications to industrial, electronics, MEMS/NEMS, and
implantable medical devices). <o:p></o:p></span></p><p class="MsoNormal" style="margin-right:-.5in;text-align:justify;text-justify:
inter-ideograph"><span lang="DE"><br></span></p>
<p class="MsoNormal" style="margin-right:-.5in;text-align:justify;text-justify:
inter-ideograph"><span lang="DE">The UNCD film technology is now commercialized for
industrial components and systems by Advanced Diamond Technologies (ADT), a
Company founded by Auciello and Carlisle, spun-off from Argonne in 2003, and by
Original Biomedical Implants (OBI), a company founded by Auciello and Gurman
(MD), in 2013, for commercializing a new generation of UNCD-coated implantable
medical devices and medical treatments based on nanotechnology.<o:p></o:p></span></p>
<p class="MsoNormal" style="margin-right:-.5in;text-align:justify;text-justify:
inter-ideograph"><span lang="DE">Auciello has edited 20 books on various topics,
published about 500 articles in the fields described above, holds 20 patents,
and organized, chaired, and lectured at numerous national and international
conferences. He is associate editor of Appl. Phys. Lett., Integrated
Ferroelectrics, and editor of two book series on thin films and applications to
devices (Academic Press). He was member the Materials Research Society (MRS)
Board of Directors (2000-2003), Co-Chair MRS International Relations Committee,
Vice President of the MRS in 2012, President in 2013, and Past President in
2014.<o:p></o:p></span></p><p class="MsoNormal" style="margin-right:-.5in;text-align:justify;text-justify:
inter-ideograph"><span lang="DE"><br></span></p>
<p class="MsoNormal" style="margin-right:-.5in;text-align:justify;text-justify:
inter-ideograph"><span lang="DE">He has numerous Awards, including seven R&D
100 Awards, 2003 Hispanic Engineering National Achievement Award, 2006 Federation
of National Laboratories Award, 2008 University of Chicago Distinguished
Performance Award, and is a Fellow of the AAAS and<b> </b>MRS. <o:p></o:p></span></p>
<p class="MsoNormal" style="margin-right:-.95pt;text-align:justify;text-justify:
inter-ideograph"><span lang="DE" style="font-size:11.0pt;mso-bidi-font-size:10.0pt;
font-family:Times"> </span></p>
<p class="MsoNormal" style="margin-right:-.95pt;text-align:justify;text-justify:
inter-ideograph"><b><span lang="DE" style="font-size:11.0pt;mso-bidi-font-size:10.0pt;font-family:Times">ABSTRACT<o:p></o:p></span></b></p>
<p class="MsoNormal" style="margin-right:-.7pt;text-align:justify;text-justify:
inter-ideograph"><span style="font-size:11.0pt;mso-bidi-font-size:10.0pt;
font-family:Times;mso-ansi-language:EN-US">New paradigms in the research and
development of novel multifunctional oxide and nanocarbon thin films are providing
the bases for new physics, new materials science and chemistry, and their
impact in a new generation of multifunctional devices for
micro/nano-electronics and biomedical devices. This talk focus on discussing
the science, technology, and engineering of multifunctional oxide and
nanocarbon thin films and applications to a new generation of multifunctional
micro and nano-devices, as described below:<o:p></o:p></span></p>
<p class="MsoNormal" style="margin-left:.25in;text-align:justify;text-justify:
inter-ideograph;text-indent:-.25in;mso-pagination:none;mso-list:l0 level1 lfo1;
mso-layout-grid-align:none"><!--[if !supportLists]--><b><span style="font-size:11.0pt;mso-bidi-font-size:10.0pt;font-family:
Times;mso-fareast-font-family:Times;mso-bidi-font-family:Times;mso-ansi-language:
EN-US">1.<span style="font-weight: normal; font-size: 7pt; font-family: 'Times New Roman'; ">
</span></span></b><!--[endif]--><b><span style="font-size:11.0pt;mso-bidi-font-size:10.0pt;font-family:Times;mso-ansi-language:
EN-US">Science and technology of complex oxide thin films and application to key
technologies: </span></b><span style="font-size:11.0pt;mso-bidi-font-size:10.0pt;
font-family:Times;mso-ansi-language:EN-US"> <o:p></o:p></span></p>
<p class="MsoNormal" style="margin-left:9.0pt;text-align:justify;text-justify:
inter-ideograph;text-indent:-9.0pt;mso-pagination:none;mso-layout-grid-align:
none"><span style="font-size:11.0pt;mso-bidi-font-size:10.0pt;font-family:Times;
mso-ansi-language:EN-US">• Novel TiO<sub>2</sub>/Al<sub>2</sub>O<sub>3</sub>
superlattices, exhibiting giant dielectric constant (up to k=1000), low leakage
current (10<sup>-7</sup>-10<sup>-9</sup> A/cm<sup>2</sup>) and low losses (≤
tang d=0.04), based on new physics underlined by the Maxwell-Wagner relaxation
mechanism, which enables a new generation of microchip embedded capacitors for
microchips implantable in the human body, the next generation of gates for
nanoscale CMOS devices, and super-capacitors for energy storage systems.<o:p></o:p></span></p>
<p class="MsoNormal" style="margin-left:9.0pt;text-align:justify;text-justify:
inter-ideograph;text-indent:-9.35pt;mso-pagination:none;mso-layout-grid-align:
none"><span style="font-size:11.0pt;mso-bidi-font-size:10.0pt;font-family:Times;
mso-ansi-language:EN-US">• </span><span style="font-size:11.0pt;font-family:
Times;mso-ansi-language:EN-US">Novel BiFeO<sub>3</sub>/SrTiO<sub>3</sub>/ BiFeO<sub>3
</sub></span><span lang="DE" style="font-size:11.0pt;font-family:Times;
mso-fareast-language:KO">nanolaminates (BSB-NL) have recently been shown to
exhibit two orders of magnitude lower leakage current than stochiometric BFO
layers, i.e., from 10<sup>-5</sup> A/cm<sup>2</sup> to 10<sup>-7</sup> A/cm<sup>2</sup>.
The BSB-NL also shows very high piezoelectric response, which is ~ 5 times
higher than that of the pure BFO with the same thickness. The strained state of
the BFO layers concurrently with the chemical and crystallographic state of the
interfaces between the BFO and STO layers contribute to the very high values of
piezoresponse and very low leakage current observed in the BSB-NLs. BSB-NL are
being integrated with the ultrananoacrystalline diamond (UNCD) films described
below to develop a new generation of implantable biosensors and piezoelectrically
actuated MEMS drug delivery devices.</span><sub><span style="font-size:11.0pt;
font-family:Times;mso-ansi-language:EN-US"><o:p></o:p></span></sub></p>
<p class="MsoNormal" style="margin-right: -0.95pt; margin-left: 22.5pt; text-align: justify; text-indent: -21pt; "><!--[if !supportLists]--><b><span style="font-size:11.0pt;mso-bidi-font-size:
10.0pt;font-family:Times;mso-fareast-font-family:Times;mso-bidi-font-family:
Times;mso-ansi-language:EN-US">2.<span style="font-weight: normal; font-size: 7pt; font-family: 'Times New Roman'; "> </span></span></b><!--[endif]--><b><span style="font-size:11.0pt;mso-bidi-font-size:
10.0pt;font-family:Times;mso-ansi-language:EN-US">Science and technology of ultrananocrystalline
diamond (UNCD) films and integration for fabrication of a new generation of
industrial devices, and high tech and biomedical devices:</span></b><span style="font-size:11.0pt;mso-bidi-font-size:10.0pt;font-family:Times;mso-ansi-language:
EN-US"> <o:p></o:p></span></p>
<p class="MsoNormal" style="margin-right:-.95pt;text-align:justify;text-justify:
inter-ideograph;text-indent:.25in"><span style="font-family:Times;mso-ansi-language:
EN-US">R&D of novel multifunctional nanocarbon thin films are providing the
bases for new physics, new materials science and chemistry, and their impact in
a new generation of multifunctional medical devices. This talk will focus on
discussing a new paradigm in multifunctional novel ultrananocrystalline diamond
(UNCD) thin films and integration into a new generation of medical devices and
implants as described below:<o:p></o:p></span></p>
<p class="MsoNormal" style="margin-right:-.7pt;text-align:justify;text-justify:
inter-ideograph"><span style="font-family:Times;mso-ansi-language:EN-US">UNCD<b> </b>films co-developed and patented by O. Auciello
and colleagues are synthesized by novel microwave plasma chemical vapor
deposition and hot filament chemical vapor deposition techniques using an
Ar-rich/CH<sub>4</sub> chemistry that produces films with 2-5 nm grains, thus
the name UNCD to distinguish them from nanocrystalline diamond films with
30-100 nm grains. The fundamental science underlying the synthesis and
properties of the UNCD films will be discussed, as well as the integration with
other materials for device fabrications. The UNCD films exhibit a unique
combination of outstanding mechanical, trtibological, electrical, thermal, and
biological properties, which already resulted in industrial components and
devices currently commercialized by Advanced Diamond Technologies (a company
co-founded by O. Auciello and colleagues in 2003, made profitable in 2014).
Devices and systems reviewed include: a) UNCD-coated mechanical pump seals,
providing up to 20% energy cost saving via friction reduction, for the
petrochemical, pharmaceutical and car industries (<b>shipping to market</b>); b) UNCD-coated bearings for mixers for the
pharmaceutical industry (<b>shipping to
Merck-Millipore market</b>); c) new electrically conductive UNCD-coated metal
electrodes for water purification system, which outperform all other electrodes
in the market today <b>(shipping to market</b>);
d) UNCD-based MEMS energy harvesting devices, biosensors and drug delivery MEMS
devices; e) New generation of Li-ion batteries with ≥ 10x longer life and
reduced size, using UNCD-based coatings technology for new anodes, membranes
and inner wall battery case chemically resistant coating; f) new generation of
medical devices (e.g., artificial retina to restore partial sight to blind
people, dental implants, hips, knees, and more) based on biocompatible UNCD
coatings. <o:p></o:p></span></p>
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