[ChBE-Grad] Today's seminar is the Rockwell Lecture — Dr. Sanat Kumar, September 27

Solano, Nicolette nsolano2 at Central.UH.EDU
Fri Sep 27 10:13:44 CDT 2024



From: UH Cullen College of Engineering <ecommunications at uh.edu>
Sent: Wednesday, September 18, 2024 10:05 AM
To: Nicolette Solano <nsolano2 at uh.edu>
Subject: Join us for the UH Cullen College Rockwell Lecture Series — Dr. Sanat Kumar, September 27


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[Mechanism of Micro and Nanoplastics Formation]<https://giving.uh.edu/page.redir?target=https%3a%2f%2fwww.egr.uh.edu%2four-college%2frockwell-lecture%2f2024%2fsanat-kumar-nae&srcid=21972&srctid=1&erid=70b8fea9-e992-4be0-8a0b-858e4e584678&trid=70b8fea9-e992-4be0-8a0b-858e4e584678>


Pradeep Sharma, Ph.D., P.E., Dean of the Cullen College of Engineering, cordially invites you to


THE ROCKWELL LECTURE SERIES:
ENGINEERING CONVERSATIONS

Mechanism of Micro and Nanoplastics Formation<https://giving.uh.edu/page.redir?target=https%3a%2f%2fwww.egr.uh.edu%2four-college%2frockwell-lecture%2f2024%2fsanat-kumar-nae&srcid=21972&srctid=1&erid=70b8fea9-e992-4be0-8a0b-858e4e584678&trid=70b8fea9-e992-4be0-8a0b-858e4e584678>


Featuring Keynote Speaker:


Sanat K. Kumar


Michael Bykhovsky and Charo Gonzalez-Bykhovsky
Professor Of Chemical Engineering
Columbia University


Event to be held in person and online.


Friday, September 27, 2024


10:30 – 11:30 a.m.


L2D2

[Rectangle: Rounded Corners: Register Now]


This lecture will be livestreamed for those who are unable to attend in person.

 


Sanat Kumar received his B.S. degree in chemical engineering from the Indian Institute of Technology in Chennai in 1981, followed by a Sc.D. from MIT in 1987. After completing a postdoctoral fellowship at IBM Almaden, he served as a faculty member at Penn State University and Rensselaer Polytechnic Institute. In 2006, he joined the Chemical Engineering Department at Columbia University, where he served as department chair from 2010 to 2016. Kumar’s research encompasses a broad range of polymeric and complex fluid systems, with a current focus on recycling polymers and mitigating nanoplastics. His work has earned him numerous honors, including visiting distinguished professorships at various international universities and the Polymer Physics Prize from the American Physical Society.

 


Lecture Abstract


It is well-established that micro and nanoplastics (MNPLs) are released from polymers through environmentally triggered bond breaking. However, the mechanism by which this Å-level process leads to nm-𝜇m sized fragments is poorly enunciated. Through experimental studies on three distinct chemistries, we demonstrate that only polymers with a semicrystalline morphology produce MNPLs under quiescent conditions. In this morphology, comprised of alternate crystalline and amorphous domains, chain scission occurs faster in amorphous regions. Through theoretical arguments, we show that tie molecules and bridging entanglements (“connectors”), which provide structural integrity to the semicrystalline structure by connecting two adjacent crystals, are preferentially broken. We propose that the cleavage of a threshold amount of connectors (i.e., scission of as little as 1% of chain bonds), leads to the spontaneous release of MNPLs.

The resulting fragments comprise highly polydisperse stacks of lamellae, with an individual lamella — tens of nanometers thick — being the building block. Degradation of the crystals occurs over much longer time scales, explaining the environmental persistence of MNPLs, even under non-quiescent conditions. Since ~70 % of polymers are semicrystalline, engineering connectors may represent an effective strategy to reduce MNPL release rates.


Presented by:

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